Yes, those are most likely crystallized nutrient salts. When the nutrient solution is drawn up from the reservoir to the surface of the clay pebbles and evaporates there, the dissolved minerals (salts) are left behind.
The symptoms on the leaves (chlorosis along the edges, rust spots on the tips and margins) indicate a problem with the uptake of mobile macro- and micronutrients. This could be caused by an incorrect pH level, which is the most common issue in hydroponic systems.
An improper pH leads to nutrient lockout — meaning the plant can’t absorb the nutrients even though they’re present in the water.
Optimal pH for hydro: 5.5 to 6.5.